Праймеріз

primary ::=  atom | attributeref | subscription | slicing | call

>>> def f(a, b):
...     print(a, b)
...
>>> f(b=1, *(2,))
2 1
>>> f(a=1, *(2,))
Traceback (most recent call last):
  File "<stdin>", line 1, in <module>
TypeError: f() got multiple values for keyword argument 'a'
>>> f(1, *(2,))
1 2